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Author (up) Fallah-Araghi, A.; Meguellati, K.; Baret, J.-C.; El Harrak, A.; Mangeat, T.; Karplus, M.; Ladame, S.; Marques, C.M.; Griffiths, A.D. openurl 
  Title Enhanced Chemical Synthesis at Soft Interfaces: A Universal Reaction-Adsorption Mechanism in Microcompartments Type Journal Article
  Year 2014 Publication Physical Review Letters Abbreviated Journal  
  Volume 112 Issue 2 Pages  
  Abstract A bimolecular synthetic reaction (imine synthesis) was performed compartmentalized in micrometer-diameter emulsion droplets. The apparent equilibrium constant (K-eq) and apparent forward rate constant (k(1)) were both inversely proportional to the droplet radius. The results are explained by a noncatalytic reaction-adsorption model in which reactants adsorb to the droplet interface with relatively low binding energies of a few k(B)T, react and diffuse back to the bulk. Reaction thermodynamics is therefore modified by compartmentalization at the mesoscale-without confinement on the molecular scale-leading to a universal mechanism for improving unfavorable reactions.  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Summary Language Original Title  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0031-9007 ISBN Medium mcube  
  Area Expedition Conference  
  Notes Times Cited: 19Griffiths, Andrew/A-1370-2010; Marques, Carlos/B-2322-2010; Baret, Jean-Christophe/E-1912-2016Marques, Carlos/0000-0002-3952-0498; Baret, Jean-Christophe/0000-0003-2048-83170201079-7114 Approved no  
  Call Number Admin @ benzerara @ Fallah-Araghi2014 Serial 13752  
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