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Author (up) Vitz, J.; Majdanski, T.C.; Meier, A.; Lutz, P.J.; Schubert, U.S. openurl 
  Title Polymerization of ethylene oxide under controlled monomer addition via a mass flow controller for tailor made polyethylene oxides Type Journal Article
  Year 2016 Publication Polymer Chemistry Abbreviated Journal Polym. Chem.  
  Volume 7 Issue 24 Pages 4063-4071  
  Keywords  
  Abstract The synthesis of polymers with controlled molecular and structural parameters is challenging due to the required purity of the chemicals and the exclusion of protic impurities and oxygen in particular in the case of an anionic process as shown here. In addition, a pressure build-up in the case of gaseous monomers must be considered as well as other safety requirements regarding explosive and very toxic materials. In the present work, ethylene oxide was used as the monomer and converted to polyethylene oxide (PEO), and subsequently polyethylene glycol (PEG) via the anionic ring opening polymerization technique (AROP). Thereby, different homopolymers with a varying chain length were successfully synthesized with narrow molar mass dispersities (D between 1.03 up to 1.09). An important aspect to mention is that the obtained molar mass of the final products matches nicely with the theoretically calculated values by the application of a customized mass flow controller suitable for liquids and gases. Two of them were recently integrated into the existing equipment together with an automation and control system, enabling the exact and controlled addition of any monomer down to 0.1 g h(-1) and up to 200 g h(-1), even against higher pressure and at different temperatures. Since the automation can be controlled online, no person has to be present during the monomer addition, which leads to improved safeness for the operator. Together with online monitoring, e.g. with FT-IR or UV/Vis, polymerizations were performed more efficiently and faster to yield, e.g., PEG/PEO, which is nowadays an important polymer used in personal, home and health care applications due to the water solubility of low molar mass PEG/PEO in combination with a very low toxicity (for molar masses above 400 g mol(-1)).  
  Address [Vitz, Juergen; Majdanski, Tobias C.; Meier, Alexander; Lutz, Pierre J.; Schubert, Ulrich S.] Univ Jena, Lab Organ & Macromol Chem IOMC, Humboldtstr 10, D-07743 Jena, Germany, Email: j.vitz@uni-jena.de;  
  Corporate Author Thesis  
  Publisher Royal Soc Chemistry Place of Publication Editor  
  Language English Summary Language Original Title  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 1759-9954 ISBN Medium  
  Area Expedition Conference  
  Notes WOS:000378270400013 Approved no  
  Call Number Admin @ benzerara @ Serial 14221  
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