Institut Charles Sadron Membre

Journal articles

titre

A Label‐Like Monolithic Organic Thermoelectric Generator Enabled by Local Inkjet Doping of Aligned Polymer Films

auteur

Nathan James Pataki, Shubhradip Guchait, Badr Jismy, Nicolas Leclerc, Adrica Kyndiah, Martin Brinkmann, Mario Caironi

article

Advanced Energy Materials, 2025, ⟨10.1002/aenm.202404656⟩

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Abstract The proliferation of distributed microelectronics and sensors necessitates adaptable, scala .....

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DOI : 10.1002/aenm.202404656

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Thermoelectric properties of a family of benzodifuranone-based conjugated copolymers in oriented thin films doped sequentially with NDMBI-H

auteur

Shubhradip Guchait, Diego Hinojosa, Nathan James Pataki, Said Oummouch, Laurent Herrmann, Mario Caironi, Michael Sommer, Martin Brinkmann

article

Advanced Electronic Materials, In press, ⟨10.1002/aelm.202500047⟩

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This study demonstrates the possibility to enhance thermoelectric properties of n-type benzodifurano .....

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DOI : 10.1002/aelm.202500047

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titre

Impact of Side Chain Chemical Structure on Doping and Thermoelectric Properties of Oriented PBTTT Thin Films

auteur

Shubhradip Guchait, Saïd Oummouch, Pablo Durand, Narayanaswamy Kamatham, Badr Jismy, Laurent Herrmann, Stéphane Mery, Nicolas Leclerc, Martin Brinkmann

article

Small, 2024, ⟨10.1002/smll.202410073⟩

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Abstract In this contribution, doping of oriented thin films is investigated for three PBTTT polymer .....

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DOI : 10.1002/smll.202410073

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Controlling conjugated polymer morphology by precise oxygen position in single-ether side chains

auteur

Pablo Durand, Huiyan Zeng, Badr Jismy, Olivier Boyron, Benoît Heinrich, Laurent Herrmann, Olivier Bardagot, Ioannis Moutsios, Alina Mariasevskaia, Alexey Melnikov, Dimitri Ivanov, Martin Brinkmann, Nicolas Leclerc

article

Materials Horizons, 2024, 11 (19), pp.4737-4746. ⟨10.1039/D4MH00492B⟩

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Recently, polar side chains have emerged as a functional tool to enhance conjugated polymer doping p .....

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DOI : 10.1039/D4MH00492B

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Phase‐Selective Doping of Oriented Regioregular Poly(3‐hexylthiophene‐2,5‐diyl) Controls Stability of Thermoelectric Properties

auteur

Shubhradip Guchait, Aditya Dash, Antoine Lemaire, Laurent Herrmann, Martijn Kemerink, Martin Brinkmann

article

Advanced Functional Materials, In press, ⟨10.1002/adfm.202404411⟩

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Abstract This study focuses on the impact of dopant location in the semicrystalline structure of reg .....

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DOI : 10.1002/adfm.202404411

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Spontaneous Modulation Doping in Semi‐Crystalline Conjugated Polymers Leads to High Conductivity at Low Doping Concentration

auteur

Aditya Dash, Shubhradip Guchait, Dorothea Scheunemann, Vishnu Vijayakumar, Nicolas Leclerc, Martin Brinkmann, Martijn Kemerink

article

Advanced Materials, 2023, ⟨10.1002/adma.202311303⟩

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Abstract The possibility to control the charge carrier density through doping is one of the defining .....

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DOI : 10.1002/adma.202311303

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Interplay between Side Chain Density and Polymer Alignment: Two Competing Strategies for Enhancing the Thermoelectric Performance of P3HT Analogues

auteur

Peter Gilhooly-Finn, Ian Jacobs, Olivier Bardagot, Yasser Zaffar, Antoine Lemaire, Shubhradip Guchait, Lu Zhang, Mark Freeley, William Neal, Fanny Richard, Matteo Palma, Natalie Banerji, Henning Sirringhaus, Martin Brinkmann, Christian Nielsen

article

Chemistry of Materials, 2023, 35 (21), pp.9029-9039. ⟨10.1021/acs.chemmater.3c01680⟩

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A series of polythiophenes with varying side chain density was synthesized, and their electrical and .....

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DOI : 10.1021/acs.chemmater.3c01680

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Controlling orientation, polymorphism, and crystallinity in thin films of poly(lactic‐acid) homopolymer and stereocomplex aligned by high temperature rubbing

auteur

Marion Brosset, Laurent Herrmann, Céline Kiefer, Thierry Falher, Martin Brinkmann

article

Journal of Applied Polymer Science, 2023, 140 (8), pp.e53532. ⟨10.1002/app.53532⟩

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High temperature rubbing is a fast and low-cost method that can align semi-crystalline polymers such .....

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DOI : 10.1002/app.53532

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Evolution of Length-Dependent Properties of Discrete n-Type Oligomers Prepared via Scalable Direct Arylation

auteur

Rukiya Matsidik, Hartmut Komber, Martin Brinkmann, Karl Sebastian Schellhammer, Frank Ortmann, Michael Sommer

article

Journal of the American Chemical Society, 2023, 145 (15), pp.8430. ⟨10.1021/jacs.3c00058⟩

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Efficient organic electronic devices are fabricated from both small molecules and disperse polymers, .....

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DOI : 10.1021/jacs.3c00058

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Preparation of oriented poly(lactic acid) thin films by a combination of high temperature rubbing and thermal annealing: Impact of annealing parameters on structure, polymorphism and morphology

auteur

Marion Brosset, Laurent Herrmann, Thierry Falher, Martin Brinkmann

article

Journal of Polymer Science, 2023, ⟨10.1002/pol.20220740⟩

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High temperature rubbing is a fast and low-cost method to prepare highly oriented films of polymers. .....

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DOI : 10.1002/pol.20220740

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Heterogeneous Oriented Structure model of thermoelectric transport in conducting polymers

auteur

Patrice Limelette, Nicolas Leclerc, Martin Brinkmann

article

Scientific Reports, 2023, 13 (1), pp.21161. ⟨10.1038/s41598-023-48353-5⟩

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Understanding transport phenomena in conducting polymers (CP) is a main issue in order to optimize t .....

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DOI : 10.1038/s41598-023-48353-5

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titre

Impact of the dopant location in the semi-crystalline structure of alternated donor–acceptor copolymers on the polarity switching p → n mechanism

auteur

Bharath Dyaga, Antoine Lemaire, Shubhradip Guchait, Huiyan Zeng, Bruno Schmaltz, Martin Brinkmann

article

Journal of Materials Chemistry C, 2023, 11 (47), pp.16554-16562. ⟨10.1039/D3TC02416D⟩

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Strong p-type doping of alternated donor–acceptor copolymers induces p → n polarity switching up .....

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DOI : 10.1039/D3TC02416D

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High-Temperature Rubbing: An Effective Method to Fabricate Large-Scale Aligned Semiconducting and Conducting Polymer Films for Applications in Organic Electronics

auteur

Shubhradip Guchait, Yuhan Zhong, Martin Brinkmann

article

Macromolecules, 2023, 56 (17), pp.6733-6757. ⟨10.1021/acs.macromol.3c01073⟩

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Conjugated polymers (CPs) are ubiquitous in plastic electronics in the form of semi-conducting and c .....

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DOI : 10.1021/acs.macromol.3c01073

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Impact of Regioregularity on Alignment and Thermoelectric Properties of Sequentially Doped and Oriented Films of Poly(3-hexylthiophene)

auteur

Shubhradip Guchait, Laurent Herrmann, Karim Kadri, Nicolas Leclerc, François Tran-Van, Martin Brinkmann

article

ACS Applied Polymer Materials, 2023, 5 (7), pp.5676-5686. ⟨10.1021/acsapm.3c00972⟩

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Alignment of conjugated polymers such as regioregular poly(3-hexylthiophene-2,5-diyl) (rr-P3HT) is a .....

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DOI : 10.1021/acsapm.3c00972

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Journal articles

titre

Optimizing chain alignment and preserving the pristine structure of single-ether based PBTTT helps improve thermoelectric properties in sequentially doped thin films

auteur

Martin Brinkmann, Pablo Durand, Shubhradip Guchait, Laurent Herrmann, Celine Kiefer, Nicolas Leclerc, Huiyan Zeng

article

Journal of Materials Chemistry C, 2022, ⟨10.1039/D2TC03600B⟩

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Doped polymer semi-conductors are of central interest in material science for their interesting char .....

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DOI : 10.1039/D2TC03600B

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titre

Single ether-based side chains in conjugated polymers: Towards power factors of 2.9 mW/m . K 2

auteur

Pablo Durand, Huiyan Zeng, Till Biskup, Vishnu Vijayakumar, Viktoriia Untilova, Céline Kiefer, Benoît Heinrich, Laurent Herrmann, Martin Brinkmann, Nicolas Leclerc

article

Advanced Energy Materials, 2022, 12 (2), pp.2103049. ⟨10.1002/aenm.202103049⟩

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Combining side chain engineering and controlled alignment of PBTTT is an effective strategy to produ .....

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DOI : 10.1002/aenm.202103049

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titre

Preferential Location of Dopants in the Amorphous Phase of Oriented Regioregular Poly(3‐hexylthiophene‐2,5‐diyl) Films Helps Reach Charge Conductivities of 3000 S cm −1

auteur

Yuhan Zhong, Viktoriia Untilova, Dominique Muller, Shubhradip Guchait, Céline Kiefer, Laurent Herrmann, Nicolas Zimmermann, Marion Brosset, Thomas Heiser, Martin Brinkmann

article

Advanced Functional Materials, 2022, 32 (30), pp.2202075. ⟨10.1002/adfm.202202075⟩

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Doping polymer semiconductors is a central topic in plastic electronics and especially in the design .....

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DOI : 10.1002/adfm.202202075

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titre

Electrical and mechanical properties of intrinsically flexible and stretchable PEDOT polymers for thermotherapy

auteur

Amélie Schultheiss, Amélie Revaux, Alexandre Carella, Martin Brinkmann, Huiyan Zeng, Renaud Demadrille, Jean-Pierre Simonato

article

ACS Applied Polymer Materials, 2021, 3 (11), pp.5942-5949. ⟨10.1021/acsapm.1c01203⟩

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For wearable applications such as electronic skin and biosensors, stretchable conductors are require .....

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DOI : 10.1021/acsapm.1c01203

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Organic and hybrid thermoelectrics

auteur

Martijn Kemerink, Christian Müller, Michael Chabinyc, Martin Brinkmann

article

Applied Physics Letters, 2021, 119 (26), pp.260401. ⟨10.1063/5.0082126⟩

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DOI : 10.1063/5.0082126

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titre

Influence of dopant size and doping method on the structure and thermoelectric properties of PBTTT films doped with F 6 TCNNQ and F 4 TCNQ

auteur

Vishnu Vijayakumar, Pablo Durand, Huiyan Zeng, Viktoriia Untilova, Laurent Herrmann, Patrick Algayer, Nicolas Leclerc, Martin Brinkmann

article

Journal of Materials Chemistry C, 2020, ⟨10.1039/d0tc02828b⟩

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DOI : 10.1039/d0tc02828b

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Rubbing and Drawing: Generic Ways to Improve the Thermoelectric Power Factor of Organic Semiconductors?

auteur

Dorothea Scheunemann, Vishnu Vijayakumar, Huiyan Zeng, Pablo Durand, Nicolas Leclerc, Martin Brinkmann, Martijn Kemerink

article

Advanced Electronic Materials, 2020, 6 (8), pp.2000218. ⟨10.1002/aelm.202000218⟩

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Highly oriented polymer films can show considerable anisotropy in the thermoelec-tric properties lea .....

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DOI : 10.1002/aelm.202000218

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Insights into the structural complexity of semi-crystalline polymer semiconductors: electron diffraction contributions

auteur

Martin Brinkmann

article

Materials Chemistry Frontiers, 2020, 4 (7), pp.1916-1929. ⟨10.1039/d0qm00230e⟩

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DOI : 10.1039/d0qm00230e

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Crystallization and OFET Performance of a Hydrogen‐Bonded Quaterthiophene

auteur

Jan Gebers, Bilal Özen, Lucia Hartmann, Michel Schaer, Stéphane Suarez, Philippe Bugnon, Rosario Scopelliti, Hans-Georg Steinrück, Oleg Konovalov, Andreas Magerl, Martin Brinkmann, Riccardo Petraglia, Piotr De Silva, Clémence Corminboeuf, Holger Frauenrath

article

Chemistry - A European Journal, 2020, ⟨10.1002/chem.201904562⟩

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Crystalline thin films of π-conjugated molecules are relevant as the active layers in organic elect .....

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DOI : 10.1002/chem.201904562

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Control of Chain Alignment and Crystallization Helps Enhance Charge Conductivities and Thermoelectric Power Factors in Sequentially Doped P3HT:F 4 TCNQ Films

auteur

Viktoriia Untilova, Till Biskup, Laure Biniek, Vishnu Vijayakumar, Martin Brinkmann

article

Macromolecules, 2020, ⟨10.1021/acs.macromol.9b02389⟩

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DOI : 10.1021/acs.macromol.9b02389

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High Thermoelectric Power Factor of Poly(3-hexylthiophene) through In-Plane Alignment and Doping with a Molybdenum Dithiolene Complex

auteur

Viktoriia Untilova, Jonna Hynynen, Anna I Hofmann, Dorothea Scheunemann, Yadong Zhang, Stephen Barlow, Martijn Kemerink, Seth R Marder, Laure Biniek, Christian Müller, Martin Brinkmann

article

Macromolecules, In press, ⟨10.1021/acs.macromol.0c01223⟩

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DOI : 10.1021/acs.macromol.0c01223

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titre

Impact of Competing Crystallization Processes on the Structure of All-Conjugated Donor–Acceptor Block Copolymers P3HT- b -PNDIT2 in Highly Oriented Thin Films

auteur

Viktoriia Untilova, Fritz Nübling, Laure Biniek, Michael Sommer, Martin Brinkmann

article

ACS Applied Polymer Materials, 2019, 1 (7), pp.1660-1671. ⟨10.1021/acsapm.9b00220⟩

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DOI : 10.1021/acsapm.9b00220

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Effect of Alkyl Side Chain Length on Doping Kinetics, Thermopower, and Charge Transport Properties in Highly Oriented F 4 TCNQ-Doped PBTTT Films

auteur

Vishnu Vijayakumar, Elena Zaborova, Laure Biniek, Huiyan Zeng, Laure Herrmann, Alain Carvalho, Olivier Boyron, Nicolas Leclerc, Martin Brinkmann

article

ACS Applied Materials & Interfaces, 2019, 11 (5), pp.4942-4953. ⟨10.1021/acsami.8b17594⟩

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Doping of polymer semiconductors such as poly(2,5-bis(3-alkylthiophen-2-yl)thieno[3,2-b]thiophene) ( .....

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DOI : 10.1021/acsami.8b17594

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Bringing Conducting Polymers to High Order: Toward Conductivities beyond 10 5 S cm −1 and Thermoelectric Power Factors of 2 mW m −1 K −2

auteur

Yuhan Zhong, Vishnu Vijayakumar, Viktoriia Untilova, Mounib Bahri, Laurent Herrmann, Laure Biniek, Nicolas Leclerc, Martin Brinkmann

article

Advanced Energy Materials, 2019, 9 (24), pp.1900266. ⟨10.1002/aenm.201900266⟩

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Here, an effective design strategy of polymer thermoelectric materials based on structural control i .....

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DOI : 10.1002/aenm.201900266

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From Isotropic to Anisotropic Conductivities in P(NDI2OD-T2) by (Electro-)Chemical Doping Strategies

auteur

Yannic Gross, Daniel Trefz, Daniel Bauer, Carsten Dingler, Vishnu Vijayakumar, Viktoriia Untilova, Laure Biniek, Martin Brinkmann, Sabine Ludwigs

article

Chemistry of Materials, 2019, 31 (9), pp.3542-3555. ⟨10.1021/acs.chemmater.9b00977⟩

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Both electrochemical and chemical doping of the n-type regioregular polymer poly{[N,N′-bis(2-octyl .....

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DOI : 10.1021/acs.chemmater.9b00977

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Block Junction-Functionalized All-Conjugated Donor–Acceptor Block Copolymers

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Fritz Nübling, Thomas Hopper, Brooke Kuei, Hartmut Komber, Viktoriia Untilova, Simon Schmidt, Martin Brinkmann, Enrique Gomez, Artem Bakulin, Michael Sommer

article

ACS Applied Materials & Interfaces, 2019, 11 (1), pp.1143-1155. ⟨10.1021/acsami.8b18608⟩

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Junction-functionalized donor–acceptor (D–A) block copolymers (BCPs) enable spatial and electron .....

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DOI : 10.1021/acsami.8b18608

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Original polymorphism in a naphthalene bisimide π-conjugated organogelator: a complex interplay between hydrogen bonding and heterocycle π-stacking

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Morgane Diebold, Elliot Christ, Laure Biniek, Lydia Karmazin, Benoît Heinrich, Christophe Contal, Suhrit Ghosh, Philippe Mesini, Martin Brinkmann

article

Journal of Materials Chemistry C, 2019, ⟨10.1039/C9TC04402G⟩

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This study focuses on the structure of different supramolecular assemblies formed in the gel phase a .....

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DOI : 10.1039/C9TC04402G

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Microstructural control suppresses thermal activation of electron transport at room temperature in polymer transistors

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Alessandro Luzio, Fritz Nübling, Jaime Martin, Daniele Fazzi, Philipp Selter, Eliot Gann, Christopher Mcneill, Martin Brinkmann, Michael Ryan Hansen, Natalie Stingelin, Michael Sommer, Mario Caironi

article

Nature Communications, 2019, 10, pp.3365. ⟨10.1038/s41467-019-11125-9⟩

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Recent demonstrations of inverted thermal activation of charge mobility in polymer field-effect tran .....

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DOI : 10.1038/s41467-019-11125-9

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Tuning Orientational Order of Highly Aggregating P(NDI2OD-T 2 ) by Solvent Vapor Annealing and Blade Coating

auteur

Daniel Trefz, Yannic Gross, Carsten Dingler, Roman Tkachov, Amer Hamidi-Sakr, Anton Kiriy, Christopher Mcneill, Martin Brinkmann, Sabine Ludwigs

article

Macromolecules, 2018, 52 (1), pp.43-54

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Structure and charge transport anisotropy of polythieno[3,4- b ]-thiophene- co -benzodithiophene (PTB7) oriented by high-temperature rubbing

auteur

Laure Biniek, Amer Hamidi-Sakr, Linda Grodd, Stéphanie Escoubas, Yannick Dappe, Souren Grigorian, Marc Schmutz, Martin Brinkmann

article

Advanced Electronic Materials, 2018, 4 (10), pp.1700480. ⟨10.1002/aelm.201700480⟩

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Structure determination in high performance polymer semiconductors such as polythieno[3,4‐b]‐thi .....

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DOI : 10.1002/aelm.201700480

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In Situ Synthesis of Ternary Block Copolymer/Homopolymer Blends for Organic Photovoltaics

auteur

Fritz Nübling, Dan Yang, Peter Müller-Buschbaum, Martin Brinkmann, Michael Sommer

article

ACS Applied Materials and Interfaces, 2018, 10 (21), pp.18149-18160. ⟨10.1021/acsami.8b04753⟩

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DOI : 10.1021/acsami.8b04753

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Poly(3-hexylthiophene) revisited – Influence of film deposition on the electrochemical behaviour and energy levels

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Kirsten Bruchlos, Daniel Trefz, Amer Hamidi-Sakr, Martin Brinkmann, Jürgen Heinze, Adrian Ruff, Sabine Ludwigs

article

Electrochimica Acta, 2018, 269, pp.299-311. ⟨10.1016/j.electacta.2018.02.126⟩

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DOI : 10.1016/j.electacta.2018.02.126

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Segregated versus Disordered Stacking in Two Low Bandgap Alternated Copolymers for Photovoltaic Applications: Impact of Polymorphism on Optical Properties

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Yuhan Zhong, Laure Biniek, Nicolas Leclerc, Stéphanie Ferry, Martin Brinkmann

article

Macromolecules, 2018, 51 (11), pp.4238-4249. ⟨10.1021/acs.macromol.8b00378⟩

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Structure–property correlations are often hampered by insufficient structural insight into the cry .....

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DOI : 10.1021/acs.macromol.8b00378

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Supramolecular organization of a H-bonded perylene bisimide organogelator determined by transmission electron microscopy, grazing incidence X-ray diffraction and polarized infra-red spectroscopy

auteur

Alexandru Sarbu, Patrick Hermet, David Maurin, David Djurado, Laure Biniek, Morgane Diebold, Jean-Louis Bantignies, Philippe Mesini, Martin Brinkmann

article

Physical Chemistry Chemical Physics, 2017, 19 (48), pp.32514-32525. ⟨10.1039/c7cp06761e⟩

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An organogelator based on a N,N′-substituted H-bonding perylenebisimide (PBI-C10) self-assembles t .....

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DOI : 10.1039/c7cp06761e

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Tuning Aggregation by Regioregularity for High-Performance n-Type P(NDI2OD-T 2 ) Donor–Acceptor Copolymers

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Yannic Gross, Daniel Trefz, Roman Tkachov, Viktoriia Untilova, Martin Brinkmann, Gisela Schulz, Sabine Ludwigs

article

Macromolecules, 2017, 50 (14), pp.5353-5366

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A Versatile Method to Fabricate Highly In-Plane Aligned Conducting Polymer Films with Anisotropic Charge Transport and Thermoelectric Properties: The Key Role of Alkyl Side Chain Layers on the Doping Mechanism

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Amer Hamidi-Sakr, Laure Biniek, Jean-Louis Bantignies, David Maurin, Laure Herrmann, Nicolas Leclerc, Patrick Lévêque, Vishnu Vijayakumar, Nicolas Zimmermann, Martin Brinkmann

article

Advanced Functional Materials, 2017, 27 (25), pp.1700173. ⟨10.1002/adfm.201700173⟩

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A general method is proposed to produce oriented and highly crystalline conducting polymer layers. I .....

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DOI : 10.1002/adfm.201700173

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Insulated molecular wires: sheathing semiconducting polymers with organic nanotubes through heterogeneous nucleation

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Gijo Raj, Athmane Boulaoued, Johann Lacava, Laure Biniek, Philippe J. Mesini, Martin Brinkmann, Jérôme Faure-Vincent, Jean-Michel Guenet

article

Advanced Electronic Materials, 2017, 3 (1), pp.1600370. ⟨10.1002/aelm.201600370⟩

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Insulated molecular wires formed from organic molecules may have promising applications in organic a .....

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DOI : 10.1002/aelm.201600370

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Charge separation in an acceptor–donor–acceptor triad material with a lamellar structure

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D. Rolland, J. C. Brauer, L. Hartmann, Laure Biniek, Martin Brinkmann, N. Banerji, H. Frauenrath

article

Journal of Materials Chemistry C, 2017, 5 (6), pp.1383-1393. ⟨10.1039/C6TC03786K⟩

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Linking covalently both electron donor and acceptor components is an efficient way to gain thermodyn .....

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DOI : 10.1039/C6TC03786K

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High-resolution noncontact AFM and Kelvin probe force microscopy investigations of self-assembled photovoltaic donor–acceptor dyads

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Benjamin Grévin, Pierre-Olivier Schwartz, Laure Biniek, Martin Brinkmann, Nicolas Leclerc, Elena Zaborova, Stéphane Méry

article

Beilstein Journal of Nanotechnology, 2016, 7, pp.799-808. ⟨10.3762/bjnano.7.71⟩

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DOI : 10.3762/bjnano.7.71

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Highly Oriented and Crystalline Films of a Phenyl-Substituted Polythiophene Prepared by Epitaxy: Structural Model and Influence of Molecular Weight

auteur

Amer Hamidi-Sakr, Daniel Schiefer, Sangeetha Covindarassou, Laure Biniek, Michael Sommer, Martin Brinkmann

article

Macromolecules, 2016, 49 (9), pp.3452-3462. ⟨10.1021/acs.macromol.6b00495⟩

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DOI : 10.1021/acs.macromol.6b00495

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Metal nanoparticle mediated space charge and its optical control in an organic hole-only device

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Giovanni Ligorio, M.V. Nardi, R. Steyrleuthner, Dris Ihiawakrim, N. Crespo-Monteiro, Martin Brinkmann, D. Neher, Norbert Koch

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Applied Physics Letters, 2016, 108 (15), ⟨10.1063/1.4945710⟩

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We reveal the role of localized space charges in hole-only devices based on an organic semiconductor .....

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DOI : 10.1063/1.4945710

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Precise Control of Lamellar Thickness in Highly Oriented Regioregular Poly(3-Hexylthiophene) Thin Films Prepared by High-Temperature Rubbing: Correlations with Optical Properties and Charge Transport

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Amer Hamidi-Sakr, Laure Biniek, Sadiara Fall, Martin Brinkmann

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Advanced Functional Materials, 2016, 26 (3), pp.408-420. ⟨10.1002/adfm.201504096⟩

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Precise control of orientation and crystallinity is achieved in regioregular poly(3-hexylthiophene) .....

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DOI : 10.1002/adfm.201504096

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Structural Models of Poly(cyclopentadithiophene- alt -benzothiadiazole) with Branched Side Chains: Impact of a Single Fluorine Atom on the Crystal Structure and Polymorphism of a Conjugated Polymer

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Florian Fischer, Navaphun Kayunkid, Daniel Trefz, Sabine Ludwigs, Martin Brinkmann

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Macromolecules, 2015, 48 (12), pp.3974-3982

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Zipper-like molecular packing of donor–acceptor conjugated co-oligomers based on perylenediimide

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Laure Biniek, Pierre-Olivier Schwartz, Elena Zaborova, Benoît Heinrich, Nicolas Leclerc, Stéphane Mery, Martin Brinkmann

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Journal of Materials Chemistry C, 2015, 3 (14), pp.3342-3349. ⟨10.1039/c5tc00221d⟩

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The molecular packing of a new class of perylene diimide-based acceptor-donor (A-D) co-oligomers has .....

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DOI : 10.1039/c5tc00221d

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3D imaging of filaments in organic resistive memory devices

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Yan Busby, N. Crespo-Monteiro, Maria Girleanu, Martin Brinkmann, Ovidiu Ersen

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Organic Electronics, 2015, 16, pp.Pages 40-45. ⟨10.1016/j.orgel.2014.10.039⟩

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Filaments in organic and hybrid resistive memories are studied by combining advanced characterizatio .....

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DOI : 10.1016/j.orgel.2014.10.039

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Reversible J- to H-aggregate transformation in thin films of a perylenebisimide organogelator

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Alexandru Sarbu, Laure Biniek, Jean-Michel Guenet, Philippe Mesini, Martin Brinkmann

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Journal of Materials Chemistry C, 2015, 3 (6), pp.1235-1242. ⟨10.1039/c4tc02444c⟩

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A perylene bisimide organogelator is shown to behave as a reversible stimuli responsive material: th .....

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DOI : 10.1039/c4tc02444c

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High-Temperature Rubbing: A Versatile Method to Align π-Conjugated Polymers without Alignment Substrate

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Laure Biniek, Stéphanie Pouget, David Djurado, Eric Gonthier, Kim Tremel, Navaphun Kayunkid, Elena Zaborova, Nicolas Crespo-Monteiro, Olivier Boyron, Nicolas Leclerc, Sabine Ludwigs, Martin Brinkmann

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Macromolecules, 2014, 47 (12), pp.3871-3879. ⟨10.1021/ma500762x⟩

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Mechanical rubbing of polymer films has been widely used in the liquid crystal display industry to p .....

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DOI : 10.1021/ma500762x

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Perylenediimide-Based Donor–Acceptor Dyads and Triads: Impact of Molecular Architecture on Self-Assembling Properties

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Pierre-Olivier Schwartz, Laure Biniek, Elena Zaborova, Benoît Heinrich, Martin Brinkmann, Nicolas Leclerc, Stéphane Mery

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Journal of the American Chemical Society, 2014, 136 (16), pp.5981-5992

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Intertwined Lamello-Columnar Coassemblies in Liquid-Crystalline Side-Chain Π-Conjugated Polymers: Toward a New Class of Nanostructured Supramolecular Organic Semiconductors

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Danli Zeng, Ibtissam Tahar-Djebbar, Yiming Xiao, Farid Kameche, Navaphun Kayunkid, Martin Brinkmann, Daniel Guillon, Benoît Heinrich, Bertrand Donnio, Dimitri A. Ivanov, Emmanuelle Lacaze, David Kreher, Fabrice Mathevet, André-Jean Attias

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Macromolecules, 2014, 47 (5), pp.1715-1731. ⟨10.1021/ma4020356⟩

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DOI : 10.1021/ma4020356

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Orienting Semi-Conducting π-Conjugated Polymers

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Martin Brinkmann, Lucia Hartmann, Laure Biniek, Kim Tremel, Navaphun Kayunkid

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Macromolecular Rapid Communications, 2014, 35 (1), pp.9-26

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Charging and exciton-mediated decharging of metal nanoparticles in organic semiconductor matrices

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Giovanni Ligorio, Marco Nardi Vittorio, Christos Christodoulou, Ileana Florea, N. Crespo-Monteiro, Ovidiu Ersen, Martin Brinkmann, Norbert Koch

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Applied Physics Letters, 2014, 104 (16), pp.163302-1. ⟨10.1063/1.4873347⟩

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Gold nanoparticles (Au-NPs) were deposited on the surface of n- and p-type organic semiconductors to .....

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DOI : 10.1063/1.4873347

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Large scale alignment and charge transport anisotropy of pBTTT films oriented by high temperature rubbing

auteur

Laure Biniek, Nicolas Leclerc, Thomas Heiser, Rony Bechara, Martin Brinkmann

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Macromolecules, 2013, 46 (10), pp. 4014-4023. ⟨10.1021/ma400516d⟩

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DOI : 10.1021/ma400516d

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Impact of Thermal Annealing on the Semicrystalline Nanomorphology of Spin-Coated Thin Films of Regioregular Poly(3-alkylthiophene)s as Observed by High-Resolution Transmission Electron Microscopy and Grazing Incidence X-ray Diffraction

auteur

Shabi Thankaraj Salammal, Eduard Mikayelyan, Souren Grigorian, Ullrich Pietsch, Nils Koenen, Ullrich Scherf, Navaphun Kayunkid, Martin Brinkmann

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Macromolecules, 2012, 45 (13), pp.5575-5585

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2D Versus 3D Crystalline Order in Thin Films of Regioregular Poly(3-hexylthiophene) Oriented by Mechanical Rubbing and Epitaxy

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Lucia Hartmann, Kim Tremel, Sureeporn Uttiya, Edward Crossland, Sabine Ludwigs, Navaphun Kayunkid, Christelle Vergnat, Martin Brinkmann

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Advanced Functional Materials, 2011, 21 (21), pp.4047-4057

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Highly Oriented and Nanotextured Films of Regioregular Poly(3-hexylthiophene) Grown by Epitaxy on the Nanostructured Surface of an Aromatic Substrate

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Martin Brinkmann, Christophe Contal, Navaphun Kayunkid, Tatjana Djuric, Roland Resel

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Macromolecules, 2010, 43 (18), pp.7604-7610. ⟨10.1021/ma101313m⟩

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A simple method for the nanotexturing and orientation of regioregular poly(3-hexylthiophene) (P3HT) .....

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DOI : 10.1021/ma101313m

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Structural Model of Regioregular Poly(3-hexylthiophene) Obtained by Electron Diffraction Analysis

auteur

Navaphun Kayunkid, Sureeporn Uttiya, Martin Brinkmann

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Macromolecules, 2010, 43 (11), pp.4961-4967

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Epitaxial Growth of Highly Oriented Fibers of Semiconducting Polymers with a Shish-Kebab-Like Superstructure

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Martin Brinkmann, Frédéric Chandezon, Robert Bernard Pansu, Carine Julien

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Advanced Functional Materials, 2009, 19 (17), pp.2759-2766. ⟨10.1002/adfm.200900966⟩

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Highly oriented fibers of regioregular poly(3-alkylthiophene)s (P3ATs) showing a ldquoshish-kebabrdq .....

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DOI : 10.1002/adfm.200900966

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Synthesis and self-assembly in bulk of six-arm star-block copolymers with a C60 core

auteur

Bruno Schmaltz, Claude Mathis, Martin Brinkmann

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Polymer, 2009, 50 (4), pp.966 - 972. ⟨10.1016/j.polymer.2008.12.034⟩

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DOI : 10.1016/j.polymer.2008.12.034

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Synthesis and self-assembly in bulk of linear and Mikto-arm star block copolymers based on polystyrene and poly(glutamic acid)

auteur

Jerome Babin, Daniel Taton, Martin Brinkmann, Sébastien Lecommandoux

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International Journal of Biological Macromolecules, 2008, 41 (4), pp.1384-1392. ⟨10.1021/ma70⟩

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Both AB linear-type and AB(2) miktoarm star-type amphiphilic block copolymers based on polystyrene ( .....

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DOI : 10.1021/ma70

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Synthesis and Self-Assembly in Bulk of Linear and Mikto-Arm Star Block Copolymers Based on Polystyrene and Poly(glutamic acid)

auteur

Jérôme Babin, Daniel Taton, Martin Brinkmann, Sébastien Lecommandoux

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Macromolecules, 2008, 41 (4), pp.1384-1392. ⟨10.1021/ma702071y⟩

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DOI : 10.1021/ma702071y

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Switching Liquid Morphologies on Linear Grooves

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Krishnacharya Khare, Stephan Herminghaus, Jean-Christophe Baret, Bruce Law, Martin Brinkmann, Ralf Seemann

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Langmuir, 2007, 23 (26), pp.12997-13006. ⟨10.1021/la701899u⟩

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DOI : 10.1021/la701899u

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Nanostructure of self-assembled rod-coil block copolymer films for photovoltaic applications

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Thomas Heiser, G. Adamopoulos, Martin Brinkmann, U. Giovanella, S. Ould-Saad, Cyril Brochon, K. van de Wetering, Georges Hadziioannou

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Thin Solid Films, 2006, 511-512, pp.219-223. ⟨10.1016/j.tsf.2005.12.134⟩

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The nanostructures of a series of rod-coil block copolymers, designed for photovoltaic applications, .....

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DOI : 10.1016/j.tsf.2005.12.134

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Controlled grafting of polymer chains onto C60 and thermal stability of the obtained materials

auteur

Claude Mathis, Bruno Schmaltz, Martin Brinkmann

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Comptes Rendus. Chimie, 2006, 9 (7-8), pp.1075 - 1084. ⟨10.1016/j.crci.2005.11.015⟩

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DOI : 10.1016/j.crci.2005.11.015

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Wettability Control of Droplet Deposition and Detachment

auteur

Jean-Christophe Baret, Martin Brinkmann

article

Physical Review Letters, 2006, 96 (14), ⟨10.1103/PhysRevLett.96.146106⟩

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The conditions for droplet deposition on plane substrates are studied using electrowetting to contin .....

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DOI : 10.1103/PhysRevLett.96.146106

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Impact of structure and morphology on charge transport in semiconducting oligomeric thin-film devices

auteur

C. Melzer, Martin Brinkmann, W. Krasnikov, Georges Hadziioannou

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ChemPhysChem, 2005, 6 (11), pp.2376-2382. ⟨10.1002/cphc.200500142⟩

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We investigated various thin-film morphologies of vacuum-deposited highly luminescent 2,5-di-n-octyl .....

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DOI : 10.1002/cphc.200500142

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Nanoscale Organization of Fullerenes by Self-Assembly in a Diblock Copolymer Host Matrix

auteur

Bruno Schmaltz, Martin Brinkmann, Claude Mathis

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Macromolecules, 2004, 37 (24), pp.9056 - 9063. ⟨10.1021/ma048421e⟩

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DOI : 10.1021/ma048421e

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